An ATAR score of 99.1 saw HSC student Jordyn Moir top the charts at Albury's Xavier High School this year.
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The secondary school had 11 students receive an ATAR of 90 or above, with four achieving above a score of 98.
Xavier High School principal Gavin Dykes said the results are some of the best the school has seen in a decade.
He praised the students for their continuous efforts in the midst of a pandemic.
"We were absolutely rapt for our year 12 cohort this year given everything they've faced," Mr Dykes said.
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"Not only the challenges of a normal year 12 year, but also given the impacts and time in online learning, our students have done an absolutely amazing job.
"We were worried for our year 12s because we knew this would impact them the most.
"They've done amazingly well."
The Border secondary school also had two of its students with subject scores in the top 10 in the state and one in the top 15.