Riverina lost its second match in the Country Colts under 18 competition on Wednesday.
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The home zone won the toss and sent Western in, but it backfired with the visitors compiling 3-221 from the 50 overs.
In reply, Riverina made130 with East Albury's Miles Hemann-Petersen making 53.
It followed a remarkable match on the opening day on Tuesday.
Greater Illawarra was bowled out for 174 from 48.5 overs with East Albury le-spinner Coby Fitzsimmons snaring 4-40.
Fitzsimmons then featured in a 105-run opening stand with Sam Smith (56).
The strongly right-hander also struck a half-century (53) as the team appeared home at 2-152, only to collapse, losing 8-19 to finish on 171.
IN OTHER NEWS:
Riverina will meet ACT Southern Districts at Alexandra Park's Ian Barker Fields in Thursday's final match.
It's the first time the Border has hosted the Colts age division.